Table of contents

This is an oxidation-reduction (redox) reaction:

2 PbII + 4 e- → 2 Pb0 (reduction)

S-II - 6 e- → SIV (oxidation)

SVI + 2 e- → SIV (reduction)

Word equation

lead(II) sulfate + lead sulfide → lead + sulfur dioxide

Input interpretation

PbS04 + PbS → Pb + SO2

lead(II) sulfate lead sulfide lead sulfur dioxide

Balanced equation

Balance the chemical equation algebraically:

PbS04 + PbS → Pb + SO2

Add stoichiometric coefficients, c, to the reactants and products:

c1PbS04 + c2PbS → c3Pb + c4SO2

Set the number of atoms in the reactants equal to the number of atoms in the products for O, Pb and S:

O: 4c1 = 2c4

Pb: c1 + c2 = c3

S: c1+ c2 = c4

Since the coefficients are relative quantities and underdetermined, choose a coefficient to set arbitrarily. To keep the coefficients small, the arbitrary value is ordinarily one. For instance, set c1 = 1 and solve the system of equations for the remaining coefficients:

c1 = 1

c2 = 1

c3 = 2 

c4 = 2

Substitute the coefficients into the chemical reaction to obtain the balanced

equation:

Answer:

PbS04 + PbS → Pb + SO2